Non-Stoichiometry of Chromium Monoarsenide.

Chromium(VI) reduction by hydrogen sulfide in aqueous media: stoichiometry and kinetics.

The objective of this work was to investigate the reaction stoichiometry, kinetics, and mechanism for Cr(VI) reduction by hydrogen sulfide in the aqueous phase. Batch experiments with excess [Cr(VI)] over [H2S]T indicated that the molar amount of sulfide required for the reduction of 1 M Cr(VI) was 1.5, suggesting the following stoichiometry: 2CrO4(2-) + 3H2S + 4H+-->2Cr(OH)3(s) + 3S(s) + 2H2O....

In situ growth of nanoparticles through control of non-stoichiometry.

Surfaces decorated with uniformly dispersed catalytically active nanoparticles play a key role in many fields, including renewable energy and catalysis. Typically, these structures are prepared by deposition techniques, but alternatively they could be made by growing the nanoparticles in situ directly from the (porous) backbone support. Here we demonstrate that growing nano-size phases from per...

Non-Stoichiometry and Calphad Modeling of Frank-Kasper Phases

One of the many singularities of Frank-Kasper phases is their ability to accommodate extremely large composition ranges by atom mixing on the different sites of the crystal structures. This phenomenon will be reviewed in the present paper with special emphasis on the experimental demonstration of this phenomenon, the theoretical calculation of disordered structures and the modeling of these pha...

commuting and non -commuting graphs of finit groups

فرض کنیمg یک گروه غیر آبلی متناهی باشد . گراف جابجایی g که با نماد نمایش داده می شود ،گرافی است ساده با مجموعه رئوس که در آن دو راس با یک یال به هم وصل می شوند اگر و تنها اگر . مکمل گراف جابجایی g راگراف نا جابجایی g می نامیم.و با نماد نشان می دهیم. گرافهای جابجایی و ناجابجایی یک گروه متناهی ،اولین بار توسطاردوش1 مطرح گردید ،ولی در سالهای اخیر به طور مفصل در مورد بحث و بررسی قرار گرفتند . در ،م...

ZIRCONIUM AND CHROMIUM ISOTOPIC SYSTEMATICS OF NON - ALLENDE CAIs